Angelina Jolie
This was a true heartbreaker for me! During the production of Mr. & Mrs. Smith in 2004, their chemistry really started to blossom. Jennifer Aniston, Brad’s ex-wife, was still with him at the time. In 2005, Pitt and Aniston divorced, and “Brangelina” was born a year later, this time with a child on the prowl. Brad and Angelina will officially call it quits on their relationship in the year 2016.
Britney Spears
In 2004, the pop diva began dating backup dancer Kevin Federline, and the two became engaged after only three months of dating. The couple has two children. The only snag was that Federline was already married to Shar Jackson, which was a minor setback. On top of all that, Shar was also pregnant with her second child with Federline at the time of the incident. However, Spears and Federline were married a few months later and went on to have two children together. Britney Spears and Kevin Federline ended their marriage in 2006.